Mr. and Mrs. Smith
Brad Pitt and Angelina Jolie famously began their romance on the set of Mr. and Mrs. Smith, much to Jennifer Aniston's chagrin. Pitt and Jolie play John and Jane, a couple with some serious secrets behind the scenes. Though Mr. and Mrs. Smith is supposed to take place in Westchester, New York, one particular scene makes it obvious that the movie was filmed was in Los Angeles.